Crystal structure of (E)-2-(tert-butylamino)-4-(tertbutylimino)naphthalen-1(4H)-one

 

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Bibliographic Details
Authors: Lamoureux Lamontagne, Guy, Alvarado Rojas, Mónica, Pineda Cedeño, Leslie William
Format: artículo original
Publication Date:2018
Description:The title compound, C18H24N2O, is the first example of a naphthoquinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The molecular conformation is stabilized by an intramolecular hydrogen bond between the amine and a carbonyl group and by London attraction between the two tert-butyl groups. Only van der Waals interactions were identified in the crystal packing
Country:Kérwá
Institution:Universidad de Costa Rica
Repositorio:Kérwá
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/76359
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018008514
https://hdl.handle.net/10669/76359
Access Level:acceso abierto
Keyword:Crystal structure
Naphtho­quinone
Intra­molecular hydrogen bonding
N—H⋯O hydrogen bonding
540 Química