Spatial distribution of heavy metals in sediments from the Gulf of Paria, Trinidad

 

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Autor: Norville, Wendy
Formato: artículo original
Estado:Versión publicada
Fecha de Publicación:2005
Descripción:The Gulf of Paria receives heavy metal input from urban runoff, industrial and agricultural activity, sewage and domestic wastes: both from the west coast and from inland areas of Trinidad. Non-residual concentrations of nine metals, as well as total mercury concentrations, were used to determine spatial distributions of heavy metals in sediments in the Gulf of Paria. Surficial sediment samples were collected at 37 stations, which included the mouths of 11 major rivers that flow into the Gulf of Paria. Stations were sampled twice during the wet season (July 1998 and November/ December 1998) and twice during the dry season (March 1999 and April 1999). Sediments were analyzed for aluminium (Al), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), lead (Pb), manganese (Mn), nickel (Ni), zinc (Zn) and mercury (Hg). Total Organic Carbon (TOC) and grain size analyses were also performed on the sediments. Principal component analysis showed that sediments from river mouths subject to greatest land use and anthropogenic input, were distinct from other sediments in the Gulf of Paria. This was due to higher Pb, Zn, Cu and Hg concentrations (3.53-73.30 μg g-1, 45.8-313.9 μg g-1, 8.43-39.71 μg g-1 and 0.03-0.10 μg g-1, respectively). Sediments further from the coast were also distinct due to their higher Al, Fe, Cr and Mn concentrations (1.37-3.16 mg g-1, 9.51-18.91 mg g-1, 17.22-28.41 μg g-1 and 323.6–1,564.2 μg g-1, respectively). Cd and Pb were higher in the wet season while Ni was higher in the dry season. Pb, Zn, Cu and Hg were correlated with each other and with TOC. Correlation was also observed between Al, Fe, Cr, Mn and Ni. Al, Fe, Cr and Mn were correlated with percentage clay in sediments. The results suggest that Pb, Zn, Cu and Hg are preferentially removed by organic matter, which settles at the river-mouths, while Al, Fe, Cr, Mn, and Ni become associated with clay minerals and are transported away from the coast.
País:Portal de Revistas UCR
Institución:Universidad de Costa Rica
Repositorio:Portal de Revistas UCR
Lenguaje:Inglés
OAI Identifier:oai:portal.ucr.ac.cr:article/26617
Acceso en línea:https://revistas.ucr.ac.cr/index.php/rbt/article/view/26617
Access Level:acceso abierto
Palabra clave:Heavy metals
spatial distribution
sediments
Trinidad
Caribbean
Metales pesados
distribución espacial
sedimentos
Caribe