1,3-Bis{[(2,6-di­methyl­phen­yl)sulfan­yl]meth­yl}benzene

 

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Detalles Bibliográficos
Autores: Garita Salazar, Bruno, Pineda Cedeño, Leslie William
Formato: artículo original
Fecha de Publicación:2019
Descripción:The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thio­phenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thio­phenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the mol­ecules into inversion dimers.
País:Kérwá
Institución:Universidad de Costa Rica
Repositorio:Kérwá
OAI Identifier:oai:https://www.kerwa.ucr.ac.cr:10669/81417
Acceso en línea:https://iucrdata.iucr.org/x/issues/2019/05/00/hb4295/index.html
https://hdl.handle.net/10669/81417
Access Level:acceso abierto
Palabra clave:Ligandos pinza
Azufre
Efecto quelato
Estabilización cinética
Crystal structure
Chelating ligand
SCS pincer ligands
Kinetic stabilization
Sulfur atom