Germacranolides from Mikania guaco

 

Shranjeno v:
Bibliografske podrobnosti
Autores: Rüngeler, Peter, Brecht, Volker, Tamayo Castillo, Giselle, Merfort, Irmgard
Format: artículo original
Fecha de Publicación:2001
Opis:Fourteen novel sesquiterpene lactones of the germacranolide type have been isolated from the aerial parts of Mikania guaco: six costunolide, two melampolide and six germacra-4-trans,10(14),11(13)-trien-12,6α-olide derivatives. Except for one compound all the others possess a carbonyl function at C-9. Eight were obtained in the form of four isomer pairs which were difficult to separate. Structure elucidation was based on mass and 1D and 2D NMR measurements. Low energy conformations were obtained by quantum mechanical calculations. Pyrrolizidine alkaloids could not be detected.
País:Kérwá
Institucija:Universidad de Costa Rica
Repositorio:Kérwá
Jezik:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/87850
Online dostop:https://www.sciencedirect.com/science/article/pii/S0031942200003940#!
https://hdl.handle.net/10669/87850
Ključna beseda:Mikania guaco
Asteraceae
Structure elucidation
Sesquiterpene lactones
Germacranolides
PHYTOCHEMISTRY