Crystal structure of 4-[(adamantan-1-yl)amino]naphthalene-1,2-dione
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| Autors: | , , |
|---|---|
| Format: | artículo original |
| Data de publicació: | 2018 |
| Descripció: | The title compound, C20H21NO2, an example of a stable 1,2-naphthoquinone, was determined by single-crystal X-ray diffraction analysis at 100 K. This structure illustrates steric buttressing of the adamantanyl group, forcing the N— H group into the coplanar aromatic C—H. The presence of strong delocalization between the planar N atom at the 4-position and the carbonyl group at the 2-position is indicated. In the crystal, C—HO and C—H interactions link the molecules into a three-dimensional network. |
| Pais: | Kérwá |
| Institution: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/76555 |
| Accés en línia: | http://scripts.iucr.org/cgi-bin/paper?S2056989018017917 https://hdl.handle.net/10669/76555 |
| Paraula clau: | Crystal structure Adamantane N— HO hydrogen bonding Intramolecular hydrogen bonding Naphthoquinone 548.81 Cristalografía estructural |