Orbitals in general chemistry, Part II: Mathematical Realities

 

Tallennettuna:
Bibliografiset tiedot
Tekijät: Lamoureux Lamontagne, Guy, Ogilvie, John F.
Aineistotyyppi: artículo original
Julkaisupäivä:2021
Kuvaus:In Part II of a three-part series, we discuss two factors absent from textbooks of general chemistry that are important in a discussion of teaching orbitals. First, atomic orbitals are shown systematically to comprise algebraic formulae in coordinates of not one but four sets (spherical polar, paraboloidal, ellipsoidal, spheroconical coordinates). Each formula has its corresponding shape as a surface of constant amplitude; some visual examples are provided. Second, the argument that molecular structure is incompatible with quantum mechanics is presented. Despite the utility of orbitals as mathematical functions in various calculations, they are intrinsically complicated for the traditional purpose of qualitative explanation of molecular structure.
Maa:Kérwá
Organisaatio:Universidad de Costa Rica
Repositorio:Kérwá
Kieli:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/86891
Linkit:http://static.sites.sbq.org.br/quimicanova.sbq.org.br/pdf/ED2020-0252.pdf
https://hdl.handle.net/10669/86891
Sanahaku:Orbitals
MOLECULAR STRUCTURE
Teaching general chemistry
CHEMISTRY
QUANTUM THEORY