La cinética de la esterificación de ácidos carboxílocos es de segundo orden con repecto al alcohol
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| Autores: | , , |
|---|---|
| Formato: | artículo original |
| Estado: | Versión publicada |
| Fecha de Publicación: | 2009 |
| Descrição: | Esterification of carboxylic acids with alcohols is considered as AAC2 type reaction. The specific rate of esterification of acetic acid with methanol, in mixtures of acetonitrile-methanol showed a quadratic dependence on the alcohol concentration. This second order dependence suggests a general base catalyzed mechanism analogous to the [H2O]2 kinetic dependence observed in the acidcatalyzed hydrolysis of carboxylic esters, in highly aqueous media. |
| País: | Portal de Revistas UCR |
| Recursos: | Universidad de Costa Rica |
| Repositorio: | Portal de Revistas UCR |
| Idioma: | Español |
| OAI Identifier: | oai:portal.ucr.ac.cr:article/2644 |
| Acesso em linha: | https://revistas.ucr.ac.cr/index.php/cienciaytecnologia/article/view/2644 |