La cinética de la esterificación de ácidos carboxílocos es de segundo orden con repecto al alcohol

 

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Библиографические подробности
Авторы: Arias Carrillo, Maynor, Céspedes Camacho, Isaac, Fatjó Rojas, Daniel
Формат: artículo original
Статус:Versión publicada
Дата публикации:2009
Описание:Esterification of carboxylic acids with alcohols is considered as AAC2 type reaction. The specific rate of esterification of acetic acid with methanol, in mixtures of acetonitrile-methanol showed a quadratic dependence on the alcohol concentration. This second order dependence suggests a general base catalyzed mechanism analogous to the [H2O]2 kinetic dependence observed in the acidcatalyzed hydrolysis of carboxylic esters, in highly aqueous media.   
Страна:Portal de Revistas UCR
Институт:Universidad de Costa Rica
Repositorio:Portal de Revistas UCR
Язык:Español
OAI Identifier:oai:portal.ucr.ac.cr:article/2644
Online-ссылка:https://revistas.ucr.ac.cr/index.php/cienciaytecnologia/article/view/2644