(J + ó)2 or J(J + 1) as functional for rotational terms in analysis of molecular spectra
Αποθηκεύτηκε σε:
| Συγγραφέας: | |
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| Μορφή: | artículo original |
| Κατάσταση: | Versión publicada |
| Ημερομηνία έκδοσης: | 2019 |
| Περιγραφή: | The theoretical and experimental evidence regarding the use of (J + 1⁄2)2 and J (J + 1) as a functional in formulae for rotational term values in the spectral analysis of a diatomic molecule in electronic state 1 Σ is scrutinised. The infrared spectra of HCl serve as examples of the application of the two functionals. The total evidence indicates that (J + 1⁄2) 2 is preferable to J (J + 1) for the stated purpose, confirming Mulliken’s statement in 1930. |
| Χώρα: | Portal de Revistas UCR |
| Ίδρυμα: | Universidad de Costa Rica |
| Repositorio: | Portal de Revistas UCR |
| Γλώσσα: | Español |
| OAI Identifier: | oai:archivo.portal.ucr.ac.cr:article/36404 |
| Διαθέσιμο Online: | https://archivo.revistas.ucr.ac.cr/index.php/cienciaytecnologia/article/view/36404 |