A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides

 

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Detaylı Bibliyografya
Yazarlar: Vásquez Céspedes, Suhelen, Cabezas Pizarro, Jorge A.
Materyal Türü: artículo original
Yayın Tarihi:2014
Diğer Bilgiler:Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with acid chlorides to produce bishomopropargylic alcohols in a single step route and with high regioselectivity and moderate yields.
Ülke:Kérwá
Kurum:Universidad de Costa Rica
Repositorio:Kérwá
Dil:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/88344
Online Erişim:https://www.sciencedirect.com/science/article/pii/S0040403914002007
https://hdl.handle.net/10669/88344
Anahtar Kelime:QUÍMICA
1,3-Dilithiopropyne
Propargyl bromide lithiation
Homopropargylation
Homopropargyl alcohols
Bishomopropargyl alcohols