A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides
সংরক্ষণ করুন:
| লেখক: | , |
|---|---|
| বিন্যাস: | artículo original |
| প্রকাশনার তারিখ: | 2014 |
| বিবরন: | Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with acid chlorides to produce bishomopropargylic alcohols in a single step route and with high regioselectivity and moderate yields. |
| দেশ: | Kérwá |
| প্রতিষ্ঠান: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| ভাষা: | Inglés |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/88344 |
| অনলাইন ব্যবহার করুন: | https://www.sciencedirect.com/science/article/pii/S0040403914002007 https://hdl.handle.net/10669/88344 |
| মুখ্য শব্দ: | QUÍMICA 1,3-Dilithiopropyne Propargyl bromide lithiation Homopropargylation Homopropargyl alcohols Bishomopropargyl alcohols |