An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia
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| Autoři: | , |
|---|---|
| Médium: | artículo original |
| Datum vydání: | 1998 |
| Popis: | (Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde. |
| Země: | Kérwá |
| Instituce: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| Jazyk: | Inglés |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/87965 |
| On-line přístup: | https://hdl.handle.net/10669/87965 |
| Klíčové slovo: | QUÍMICA ANÁLISIS QUÍMICO HORMONA COMPUESTO QUÍMICO |