An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia

 

Guardado en:
Bibliografiske detaljer
Autores: Cabezas Pizarro, Jorge A., Oehlschlager, Allan Cameron
Format: artículo original
Fecha de Publicación:1998
Beskrivelse:(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde.
País:Kérwá
Institution:Universidad de Costa Rica
Repositorio:Kérwá
Sprog:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/87965
Online adgang:https://hdl.handle.net/10669/87965
Palabra clave:QUÍMICA
ANÁLISIS QUÍMICO
HORMONA
COMPUESTO QUÍMICO