An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia
Saved in:
| Authors: | , |
|---|---|
| Format: | artículo original |
| Publication Date: | 1998 |
| Description: | (Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde. |
| Country: | Kérwá |
| Institution: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| Language: | Inglés |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/87965 |
| Online Access: | https://hdl.handle.net/10669/87965 |
| Keyword: | QUÍMICA ANÁLISIS QUÍMICO HORMONA COMPUESTO QUÍMICO |