An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia

 

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書誌詳細
著者: Cabezas Pizarro, Jorge A., Oehlschlager, Allan Cameron
フォーマット: artículo original
出版日付:1998
その他の書誌記述:(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde.
国:Kérwá
機関:Universidad de Costa Rica
Repositorio:Kérwá
言語:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/87965
オンライン・アクセス:https://hdl.handle.net/10669/87965
キーワード:QUÍMICA
ANÁLISIS QUÍMICO
HORMONA
COMPUESTO QUÍMICO