An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia

 

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Opis bibliograficzny
Autorzy: Cabezas Pizarro, Jorge A., Oehlschlager, Allan Cameron
Format: artículo original
Data wydania:1998
Opis:(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde.
Kraj:Kérwá
Instytucja:Universidad de Costa Rica
Repositorio:Kérwá
Język:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/87965
Dostęp online:https://hdl.handle.net/10669/87965
Słowo kluczowe:QUÍMICA
ANÁLISIS QUÍMICO
HORMONA
COMPUESTO QUÍMICO