Pheromone chirality of african palm weevil, Rhynchophorus phoenicis (F.) and palmetto weevil, Rhynthophorus crueniatus (F.) (Coleoptera: Curculionidae)

 

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Detalles Bibliográficos
Autores: Pérez Sánchez, Alice Lorena, Gries, Gerhard, Gries, Regine, Giblin Davis, Robin M., Oehlschlager, Allan Cameron
Formato: artículo original
Fecha de Publicación:1994
Descripción:There are four stereoisomers of both 3-methyl-octan-4-ol, the aggregation pheromone of the African palm weevil,Rhynchophorus phoenicis (F.) and 5-methyl-octan-4-ol, the aggregation pheromone of the palmetto weevil,Rhynchophorus cruentatus (F.). Synthetic stereoisomers of 3-methyl-octan-4-ol and 5-methyl-octan-4-ol were baseline-separated on a Cyclodex-B fused silica column. Use of this column in gas chromatographic-electroantennographic detection (GC-EAD) and GC-mass spectrometric (GC-MS) analyses revealed that only one stereoisomer, (3S,4S)-3-methyl-octan-4-ol and (4S,5S)-5-methyl-octan-4-ol, is produced by maleR. phoenicis and maleR. cruentatus, respectively, and elicits good antennal responses by conspecific male and female weevils. In field trapping experiments, withR. phoenicis in Côte d'Ivoire andR. cruentatus in Florida, (3S,4S)-3-methyl-octan-4-ol and (4S,5S)-5-methyl-octan-4-ol strongly enhanced attraction of fresh palm tissue, whereas other stereoisomers were behaviorally benign. Stereoisomeric 3-methyl-octan-4-ol and 5-methyl-octan-4-ol may be utilized to monitor and/or manage populations of these two palm weevils.
País:Kérwá
Institución:Universidad de Costa Rica
Repositorio:Kérwá
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/28138
Acceso en línea:http://link.springer.com/article/10.1007%2FBF02036199
https://hdl.handle.net/10669/28138
Palabra clave:Coleoptera
Curculionidae
Rhynchophorus phoenicis
Rhynchophorus cruentatus
Pheromone chirality
Aggregation pheromone
(3R,4R)-3-methyl-octan-4-ol
(3S,4S)-3-methyl-octan-4-ol
(3S,4R)-3-methyl-octan-4-ol
(3R,4S)-3-methyl-octan-4-ol
(4S,5S)-5-methyl-octan-4-ol
(4R,5R)-5-methyl-octan-4-ol
(4S,5R)-5-methyl-octan-4-ol
(4R,5S)-5-methyl-octan-4-ol