Pheromone chirality of african palm weevil, Rhynchophorus phoenicis (F.) and palmetto weevil, Rhynthophorus crueniatus (F.) (Coleoptera: Curculionidae)

 

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Bibliografske podrobnosti
Autores: Pérez Sánchez, Alice Lorena, Gries, Gerhard, Gries, Regine, Giblin Davis, Robin M., Oehlschlager, Allan Cameron
Format: artículo original
Fecha de Publicación:1994
Opis:There are four stereoisomers of both 3-methyl-octan-4-ol, the aggregation pheromone of the African palm weevil,Rhynchophorus phoenicis (F.) and 5-methyl-octan-4-ol, the aggregation pheromone of the palmetto weevil,Rhynchophorus cruentatus (F.). Synthetic stereoisomers of 3-methyl-octan-4-ol and 5-methyl-octan-4-ol were baseline-separated on a Cyclodex-B fused silica column. Use of this column in gas chromatographic-electroantennographic detection (GC-EAD) and GC-mass spectrometric (GC-MS) analyses revealed that only one stereoisomer, (3S,4S)-3-methyl-octan-4-ol and (4S,5S)-5-methyl-octan-4-ol, is produced by maleR. phoenicis and maleR. cruentatus, respectively, and elicits good antennal responses by conspecific male and female weevils. In field trapping experiments, withR. phoenicis in Côte d'Ivoire andR. cruentatus in Florida, (3S,4S)-3-methyl-octan-4-ol and (4S,5S)-5-methyl-octan-4-ol strongly enhanced attraction of fresh palm tissue, whereas other stereoisomers were behaviorally benign. Stereoisomeric 3-methyl-octan-4-ol and 5-methyl-octan-4-ol may be utilized to monitor and/or manage populations of these two palm weevils.
País:Kérwá
Institucija:Universidad de Costa Rica
Repositorio:Kérwá
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/28138
Online dostop:http://link.springer.com/article/10.1007%2FBF02036199
https://hdl.handle.net/10669/28138
https://doi.org/10.1007/BF02036199
Ključna beseda:Coleoptera
Curculionidae
Rhynchophorus phoenicis
Rhynchophorus cruentatus
Pheromone chirality
Aggregation pheromone
(3R,4R)-3-methyl-octan-4-ol
(3S,4S)-3-methyl-octan-4-ol
(3S,4R)-3-methyl-octan-4-ol
(3R,4S)-3-methyl-octan-4-ol
(4S,5S)-5-methyl-octan-4-ol
(4R,5R)-5-methyl-octan-4-ol
(4S,5R)-5-methyl-octan-4-ol
(4R,5S)-5-methyl-octan-4-ol