1,3-Bis{[(2,6-dimethylphenyl)sulfanyl]methyl}benzene
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| Autores: | , |
|---|---|
| Formato: | artículo original |
| Fecha de Publicación: | 2019 |
| Descripción: | The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thiophenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thiophenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the molecules into inversion dimers. |
| País: | Kérwá |
| Institución: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/81417 |
| Acceso en línea: | https://iucrdata.iucr.org/x/issues/2019/05/00/hb4295/index.html https://hdl.handle.net/10669/81417 |
| Palabra clave: | Ligandos pinza Azufre Efecto quelato Estabilización cinética Crystal structure Chelating ligand SCS pincer ligands Kinetic stabilization Sulfur atom |