Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
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| Autores: | , , , |
|---|---|
| Formato: | artículo original |
| Fecha de Publicación: | 2013 |
| Descripción: | Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3. Graphical abstract Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex [Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3. |
| País: | Kérwá |
| Institución: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/76361 |
| Acceso en línea: | https://www.sciencedirect.com/science/article/pii/S0277538713001113?via%3Dihub#! https://hdl.handle.net/10669/76361 |
| Palabra clave: | Magnetism Microwave assisted synthesis Coordination chemistry George Christou 60th birthday special issue 543.085 82 Espectroscopia de microondas |