Effect of Preparation Method on Catalytic Activity of Ni/ γ-Al2O3 Catalysts
محفوظ في:
| المؤلف: | |
|---|---|
| التنسيق: | artículo original |
| الحالة: | Versión publicada |
| تاريخ النشر: | 2017 |
| الوصف: | The performance of catalysts has been shown to be strongly dependent on their methods of preparation. A study to examine the relationship between catalyst preparation procedures and the structure, dispersion, activity, and selectivity of the finished catalyst is reported. 10 wt.% Ni/γ-Al2O3 catalysts were prepared by incipient wetness impregnation and by wet impregnation. The catalysts were used in the conversion of glycerol in gas phase and atmospheric pressure. The selectivity and activity of the catalysts were affected by the preparation method employed. The catalysts were characterized by TGA, TPR, N2-physorption, H2-chemisorption, XRD, TEM, FTIR and TPO. The Ni particle size and dispersion of the catalysts affected the selectivity to hydrogenolysis and dehydration routes, and the formation of carbon deposits was also affected. |
| البلد: | Portal de Revistas UCR |
| المؤسسة: | Universidad de Costa Rica |
| Repositorio: | Portal de Revistas UCR |
| اللغة: | Inglés |
| OAI Identifier: | oai:portal.ucr.ac.cr:article/23189 |
| الوصول للمادة أونلاين: | https://revistas.ucr.ac.cr/index.php/ingenieria/article/view/23189 |
| كلمة مفتاحية: | catalyst preparation nickel hydrogenolysis dehydration glycerol Presión atmosférica níquel glicerina adsorción hidrogenolisis catalizadores. |