Quantitative assessment of aldehydes in air and rainwater: a case study in natural conservation area of Costa Rica

 

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Detalles Bibliográficos
Autores: Araya-Araya, Melissa, Sibaja-Brenes, José Pablo, Soto-Fallas, Roy, Mora-Barrantes, José Carlos, Alfaro-Solís, Rosa, Borbón-Alpizar, Henry, Valde´s-González, Juan
Formato: artículo original
Fecha de Publicación:2023
Descripción:Aldehydes in the environment are among most organic compounds that participate in photochemical reactions, mainly forming radicals in significant quantities. These have harmful effects on the health of the inhabitants of cities with polluted atmospheres, mainly formaldehyde and acetaldehyde. In the present work, the concentration of seven aldehydes in air and rainwater samples in a conservation area of Costa Rica (Los Cusingos Biological Reserve, located in the South Pacific, Pérez Zeledón) was determined during 2017. For the sampling and analysis of the aldehydes, the TO-11A (EPA) method was used. Sampling used adsorption cartridges coated with a 2,4-dinitrophenylhydrazine (2,4-DNFH) solution. The samples were quantified by means of a liquid chromatograph coupled to a UV-Visible detector. The highest aldehyde concentrations in air samples correspond to formaldehyde (62.2 ± 3.1 μg/m3), acetaldehyde (88.1 ± 4.9 μg/m3) and acrolein (102.2 ± 5.2 μg/m3) during 4 hours of sampling. Heptanal was determined to be the least contributory aldehyde, as it was below the detection limit. The only aldehyde quantified in the rainwater samples was formaldehyde. The results obtained in the air sample suggest an increase in the concentration of aldehydes correlated with solar radiation and temperature, suggesting as the main contributor the photochemical reactions that take place in the air with precursor hydrocarbons.
País:RepositorioTEC
Institución:Instituto Tecnológico de Costa Rica
Repositorio:RepositorioTEC
Lenguaje:Español
OAI Identifier:oai:repositoriotec.tec.ac.cr:2238/14501
Acceso en línea:https://revistas.tec.ac.cr/index.php/tec_marcha/article/view/5993
https://hdl.handle.net/2238/14501
Palabra clave:Aldehydes
acetaldehyde
formaldehyde
forest
Chromatograph
UV-detector
Aldehídos
acetaldehído
formaldehído
bosque
cromatografía
detector UV