Biocomposite Films of Polylactic Acid Reinforced with Microcrystalline Cellulose from Pineapple Leaf Fibers

 

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Detalles Bibliográficos
Autores: Moreno, Galia, RAMÍREZ-AMADOR, KARLA, ESQUIVEL ALFARO, MARIANELLY, Jimenez, Guillermo
Formato: artículo
Fecha de Publicación:2019
Descripción:Poly(lactic acid) (PLA) composite films reinforced with microcrystalline cellulose (MCC) extracted from pineapple leaf fibers (PALF) were prepared by a solution casting procedure. In an attempt to improve the interaction between PLA and cellulose, two approaches were adopted; first, poly(ethylene glycol) (PEG) was used as a surfactant, and second, the cellulosic fibers were pre-treated using tert-butanol (TBA). Lignocellulosic and cellulosic substrates were characterized using Fourier transform infrared (FTIR), wide-angle X-ray scattering (WAXS), and hermogravimetrical analysis (TGA). MCC from PALF showed good thermal stability, left few residues after decomposing, and exhibited high crystallinity index. Mechanical, thermal and thermomechanical properties of the PLA composites were also evaluated. Multiple PLA endotherms were observed in composites with TBA-treated MCC due to crystal nucleation effects. The ultimate tensile strain values for all composites were lower than that of the pristine PLA. However, 4 wt. % MCC content provided balanced engineering properties in terms of static and dynamic tensile properties.
País:Repositorio UNA
Institución:Universidad Nacional de Costa Rica
Repositorio:Repositorio UNA
Lenguaje:Inglés
OAI Identifier:oai:null:11056/22320
Acceso en línea:http://hdl.handle.net/11056/22320
Palabra clave:CELLULOSE
COMPOSITES
MICROCRYSTALLINE
PLA
PINEAPPLE