A combined first-principles computational/experimental study on LiNi 0.66Co 0.17Mn 0.17O 2 as a potential layered cathode material
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| Autores: | , , , , , , |
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| Formato: | artículo |
| Fecha de Publicación: | 2012 |
| Descripción: | First-principles calculations are used to analyze the phase stability, formation energy, and Li intercalation potential for a series of layered cathode materials. The calculations show LiNi 0.66Co 0.17Mn 0.17O 2 as a promising cathode for lithium-ion batteries. The layer-structured LiNi 0.66Co 0.17Mn 0.17O 2 is prepared via wet chemical route, followed by annealing at 1123 K and characterized using powder X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. The characterization techniques reveal single-phase LiNi 0.66Co 0.17Mn 0.17O 2 with highly ordered structure. Galvanostatic charge-discharge curves recorded at 1C show the discharge capacity of ca. 167 mAh g -1 and good cyclic performance for 25 cycles. |
| País: | Repositorio UNA |
| Institución: | Universidad Nacional de Costa Rica |
| Repositorio: | Repositorio UNA |
| Lenguaje: | Inglés |
| OAI Identifier: | oai:https://repositorio.una.ac.cr:11056/18827 |
| Acceso en línea: | http://hdl.handle.net/11056/18827 |
| Access Level: | acceso abierto |
| Palabra clave: | LITTIUM-ION BATTERIES LAYERED CATHODE CÁLCULOS LITIO MICROSCOPÍA ELECTRÓNICA ESPECTROSCOPÍA |