Regiospecific Palladium-Catalyzed Cross-Coupling Reactions Using the Operational Equivalent of 1,3-Dilithiopropyne

 

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Библиографические подробности
Авторы: Cabezas Pizarro, Jorge A., Ferllini, Natasha
Формат: artículo original
Дата публикации:2020
Описание:A regiospecific palladium-catalyzed cross-coupling reaction using the operational equivalent of the dianion 1,3-dilithiopropyne, with aromatic iodides is reported. This reaction gives high yields of 1-propyn-1-yl-benzenes and 2-(propyn-1-yl)thiophenes in the presence of catalytic amounts of palladium(0) or (II) and stoichiometric amounts of copper iodide. No terminal alkyne or allene isomers were detected. Reaction conditions were very mild and several functional groups were tolerated.
Страна:Kérwá
Институт:Universidad de Costa Rica
Repositorio:Kérwá
Язык:Inglés
OAI Identifier:oai:kerwa.ucr.ac.cr:10669/88446
Online-ссылка:https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0039-1690895
https://hdl.handle.net/10669/88446
Ключевое слово:CHEMISTRY