A new method for the preparation of 1,3-dilithiopropyne: an efficient synthesis of homopropargyl alcohols
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| Autoři: | , , |
|---|---|
| Médium: | artículo original |
| Datum vydání: | 2001 |
| Popis: | Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with aldehydes and ketones to produce homopropargyl alcohols in a single step route and in high yields. Controlled dilithiation of propargyl bromide with n-BuLi, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with aldehydes and ketones to produce homopropargyl alcohols in a single step route in high yields. |
| Země: | Kérwá |
| Instituce: | Universidad de Costa Rica |
| Repositorio: | Kérwá |
| Jazyk: | Inglés |
| OAI Identifier: | oai:kerwa.ucr.ac.cr:10669/87962 |
| On-line přístup: | https://www.sciencedirect.com/science/article/pii/S0040403901014290 https://hdl.handle.net/10669/87962 |
| Klíčové slovo: | CHEMICAL ANALYSIS CHEMICAL PROCESSES CHEMISTRY CHEMICAL ELEMENTS |