Validation of an analytical method for the determination of polycyclic aromatic hydrocarbons by high efficiency liquid chromatography in PM10 and PM2, 5

 

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Autori: Herrera-Murillo, Jorge, Chaves-Villalobos, María del Carmen
Natura: artículo original
Status:Versión publicada
Data di pubblicazione:2012
Descrizione:An analytical method for polycyclic aromatic hydrocarbons in PM10 and PM 2.5 par ticles collected from air by high performance liquid chromatography (HPLC) was validated. The PAHs analyzed in the methodology include: Naphthalene, Acenaphthylene, Fluorene, Acenaphthene, Phenanthrene, Anthracene, fluoranthene,pyrene,Benzo(a)anthracene,Chrysene, Benzo (b)fluoranthene, Benzo (k)fluoranthene, Benzo (a)pyrene Dibenzo (a, h)anthracene, Benzo (g, h, i)perylene and Indeno (1,2,3-CD)pyrene. For these compounds, the detection limit and quantification limit were between 0,02 and 0,1 mg/l using a DIONEX ICS 3000 model cromatograph, that has two in serie detectors: UV/Vis and Fluorescense, separating the different absorption and emission signals for proper identification of individual compounds. For all the compounds analyzed the recovery factor was not significantly different from each other and the repeatability and reproducibility was found to be suitable for an analytical method, especially for the lighter PAHs.
Stato:Portal de Revistas TEC
Istituzione:Instituto Tecnológico de Costa Rica
Repositorio:Portal de Revistas TEC
Lingua:Español
OAI Identifier:oai:ojs.pkp.sfu.ca:article/456
Accesso online:https://revistas.tec.ac.cr/index.php/tec_marcha/article/view/456
Keyword:Validación
cromatografía líquida de alta eficiencia
hidrocarburos aromáticos policíclicos
partículas.
Validation
high performance liquid cromatography
policiclic aromatic hydrocarbons
particles.