Diterpenos y otros constituyentes de Croton hirtus (Euphorbiaceae)

 

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Detaylı Bibliyografya
Yazarlar: Fuentes, J C, Jakupovic, J., Murillo, R.
Materyal Türü: artículo original
Durum:Versión publicada
Yayın Tarihi:2004
Diğer Bilgiler:The roots of Croton hirtus (Euphorbiaceae) collected in Paraiso, Cartago (Costa Rica) afforded, in addition to the few known metabolites, 20 new compounds: the bis-nor dolabradane 1, the dolabradanes 2 and 3, the kauranes 4-7, the cyclopropakauranes 8 and 9, the hirtusanes 10-15, the germacradiene esters 16-18 and the C-25 compound 21, presumably formed by a Diels-Alder reaction between compound 18 and a monoterpene. All structures were elucidated using high field 1D and 2D NMR techniques. MS fragmentation patterns are here reported. The absolute configurations of 4 and 9 were elucidated by using circular dichroism. The separation was performed with modern chromatographic technics.
Ülke:Portal de Revistas UCR
Kurum:Universidad de Costa Rica
Repositorio:Portal de Revistas UCR
Dil:Español
OAI Identifier:oai:portal.ucr.ac.cr:article/14943
Online Erişim:https://revistas.ucr.ac.cr/index.php/rbt/article/view/14943
Anahtar Kelime:croton hirtus
euphorbiaceae
diterpenes
kauranes
3
18-cyclopropakaurane
hirtusane
sesquiterpenes