Diterpenos y otros constituyentes de Croton hirtus (Euphorbiaceae)
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| Auteurs: | , , |
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| Format: | artículo original |
| Statut: | Versión publicada |
| Date de publication: | 2004 |
| Description: | The roots of Croton hirtus (Euphorbiaceae) collected in Paraiso, Cartago (Costa Rica) afforded, in addition to the few known metabolites, 20 new compounds: the bis-nor dolabradane 1, the dolabradanes 2 and 3, the kauranes 4-7, the cyclopropakauranes 8 and 9, the hirtusanes 10-15, the germacradiene esters 16-18 and the C-25 compound 21, presumably formed by a Diels-Alder reaction between compound 18 and a monoterpene. All structures were elucidated using high field 1D and 2D NMR techniques. MS fragmentation patterns are here reported. The absolute configurations of 4 and 9 were elucidated by using circular dichroism. The separation was performed with modern chromatographic technics. |
| Pays: | Portal de Revistas UCR |
| Institution: | Universidad de Costa Rica |
| Repositorio: | Portal de Revistas UCR |
| Langue: | Español |
| OAI Identifier: | oai:portal.ucr.ac.cr:article/14943 |
| Accès en ligne: | https://revistas.ucr.ac.cr/index.php/rbt/article/view/14943 |
| Mots-clés: | croton hirtus euphorbiaceae diterpenes kauranes 3 18-cyclopropakaurane hirtusane sesquiterpenes |